Inside Cover: Silver(I)-Catalyzed Three-Component Reaction of Propargylic Alcohols, Carbon Dioxide and Monohydric Alcohols: Thermodynamically Feasible Access to β-Oxopropyl Carbonates (Chem. Asian J. 14/2016)
نویسندگان
چکیده
منابع مشابه
Iron-catalyzed carbometalation of propargylic and homopropargylic alcohols.
Nucleophilic addition to alkynes represents an attractive approach to the synthesis of olefins. Obstacles to this strategy include the low reactivity of alkynes toward many organometallic reagents and difficulties associated with controlling the regioselectivity of addition. Here we demonstrate that Fe(III) salts are effective precatalysts for the carbometalation of alkynes. Primary and seconda...
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Hydrozirconation of alkynes with Cp2ZrH(Cl) (Schwartz reagent) generates vinyl zirconium species reliably, stereospecifically, and regioselectively. These organometallic reagents can participate in cross-coupling reactions, conjugate and nucleophilic additions, and can undergo carbonylation and halogenation.1 Hydrozirconation of terminal alkynes often proceeds with >50:1 selectivity to form the...
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The activity of HBF4 (aqueous solution) as a catalyst in propargylation reactions is presented. Diverse types of nucleophiles were employed in order to form new C-O, C-N and C-C bonds in technical acetone and in air. Good to excellent yields and good chemoselectivities were obtained using low acid loading (typically 1 mol-%) under simple reaction conditions.
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An unprecedented silver-catalyzed cascade reaction of tosylmethyl isocyanide (TosMIC) with propargylic alcohols for the efficient synthesis of (E)-vinyl sulfones has been developed where TosMIC plays a dual role as both the reactant in the allenylation of propargylic alcohols and the sulfonyl source.
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Aliphatic alcohols of chain lengths of 24–34 carbons have been found to be beneficial in treating hypercholesterolemia. Approximately 40% of beeswax is long-chain esters which can be transesterified in supercritical carbon dioxide to give these alcohols and fatty acid methyl esters. The methanolysis reaction was catalyzed by an immobilized lipase from Candida antarctica in flowing supercritical...
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ژورنال
عنوان ژورنال: Chemistry - An Asian Journal
سال: 2016
ISSN: 1861-4728
DOI: 10.1002/asia.201600926